Hydroformylation is the process by which an olefin (alkene) reacts with syngas (CO and H2) to form an aldehyde. Also commonly known as the “Oxo” process, hydroformylation is the first step in the production of oxo alcohols with the intermediate aldehyde converted to an alcohol by hydrogenation. An alternative intermediate step is the addition of two aldehydes together to obtain a larger aldehyde, a process commonly known as aldolisation with the resultant larger aldehyde converted to an alcohol by hydrogenation. Hydroformylation is a key part of the oxo alcohols process.

Hydroformylation in the oxo alcohols process

Butyraldehyde is produced by reacting propylene with carbon monoxide and hydrogen. The major product is the straight chain normal-butyraldehyde with a smaller amount of branched chain iso-butyraldehyde. The reactions are carried out at mild temperatur (< 100°C) and low pressure (< 20 bara) in the presence of a homogeneous rhodium based catalyst with a phosphine ligand in the case of LP Oxo SELECTORSM 10 technology to provide a normal-butyraldehyde isomer ratio of 10:1. An alternative is the LP Oxo SELECTORSM 30 technology which enables a normal to isomer ratio of 30:1 utilizing the proprietary NORMAX™ Catalyst, an organophosphite ligand available from Dow.

Hydroformylation eq2 LARGER 23SEP2015


Hydroformylation eq1 LARGER 23SEP2015


NORMAX is a trademark of The Dow Chemical Company. 

LP Oxo and SELECTOR are servicemarks of The Dow Chemical Company.





















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